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If, on the other hand, the oxidation-state changes take place within an intermediate product in which the two metals are directly bonded to a common bridging group (such as shown in the equation above), the mechanism is inner-sphere.
A more acceptable description of the OH transfer mechanism, therefore, is to regard OH− as a bridging group through which electron transfer is accomplished as the two metal ion groups share a bonded oxygen atom.
In this precursor molecule two Si atoms are bound to one organic bridging group (T site) while one Si is bound to two organic bridging groups (D site).
The improvement in performance of the designed dyes suggests that additional donor is a potential bridging group for efficient multi-anchoring sensitizers.
The influence of the bridging group between the mesogenic group and the oxirane ring on the curing behavior and the liquid crystalline phase of liquid crystalline epoxy (LCE) resins was investigated.
Moreover, when replacing the CO bridging group by the CS one, in all oligomers the HOMO LUMO energy gap is reduced, due mainly to the strongest stabilization of the LUMO.
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The nanostructured bridged organoniobosilicates have been synthesized by the acid catalyzed hydrolysis and condensation of bridged silsesquioxane precursors containing two different organic bridging groups ((C2H5O 3Si R Si OC2H5 3, R: ethylene or octylene) in the presence of nonionic template P123.
Most of Cram's hemicarcerands possess four identical bridging groups, which is synthetically easier to achieve than dual- or triply-bridged hosts.
Jaroniek reported PMOs with multiple bridging groups and spherical morphologies [22, 23].
Two LCE resins containing ether and ester bridging groups were synthesized for this purpose.
Complex 1 has a remarkable structure with unusual diversity of bridging groups including triazenide molecules, OH− groups and –OCH3 groups.
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