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Small-scale breakthrough testing was conducted with CuBTC against ammonia, which probes the reactive sites, and UiO-66 against octane, which probes physical adsorption capacity.
The capability of these materials to remove ammonia, cyanogen chloride, and sulfur dioxide from air has been evaluated via fixed-bed breakthrough testing in both dry and humid conditions.
Each cycle of breakthrough testing contained entrapment of mixed gas in the gas chamber and allowing the fiber membrane placed inside to adsorb it.
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Column breakthrough tests demonstrated that the CMC-FeS ENPs were highly mobile in the tested soil, even without the use of an external pressure (i.e., just via gravitational percolation).
The results were validated by means of experimental breakthrough tests in a fixed-bed set-up.
The performance of materials as H2S adsorbents was tested using a home-developed dynamic breakthrough test.
Octane breakthrough tests were performed to determine the physisorption capacities of the materials.
Gas breakthrough tests show that no continuous gas flow was detected during the entire gas breakthrough test (until the gas pressure of 10 MPa), which indicates that the compacted bentonite/sand mixture has a good sealing ability after full saturation.
Breakthrough test was performed on two kinds of halide sorbents at accelerated condition and on honeycomb desulfurization sorbent at varied space velocity condition.
A series of column breakthrough tests at varying hydraulic residence times revealed a clear peak adsorption capacity at a Damköhler number of 2.74.
The Péclet numbers for the column breakthrough tests indicated that mechanical dispersion is an important effect that requires further consideration in the scaling-up process.
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