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Two types of dendrimers with AB2 branching, one with acyloxysilanes at the branching position (V type) and the other at the non-branching position (Y type), were synthesized using hydrosilylation with chlorosilanes followed by heterofunctional condensation with olefin-functional carboxylic acids, and examined as readily degradable template materials.
It is observed that the influence of the branching position on the glass transition temperature and mechanical properties is significantly higher than the length of the side chain.
In contrast, the two different plastid-localized ASA beta subunits seem to be cyanobacterial-derived in Viridiplantae and Glaucophyta (Fig. 3b; no BS); however, the branching position of the red algal sequences is not well resolved (Supplementary Fig. S14).
Pgo-SERA2 was located at the earliest branching position in Group IV SERA genes (Figure 2).
The branching position of Syn.
The branching position shown in Figure 11 suggests that the duplication preceded speciation.
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Due to this, black positions are also called branching positions.
All three methods gave very similar tree topologies except for the branching positions of M. kandleri and Methanospirillum hungatei, which were found to be variable.
Compounds were characterized using diagnostic ions and Kovats indices (Carlson et al. 1998) and were compared to published data to confirm assignment of the branching positions.
These studies have proven very useful in establishing the existence of certain important clades within the sequenced cyanobacteria and in clarifying their relative branching positions [ 4, 11, 12].
These cliques were identical in all respects except that the relative branching positions of Chlorobaculum tepidum and Chlorobium chlorochromatii, which differed by a single character, were interchanged.
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