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Ag+ is substituted for H+ which was previously bound to nitrogen atom in guanine.
In that temperature range, the increased catalytic activity originates from the well dispersed N4-metal moiety or from fragments of the original molecule still containing the metal bound to nitrogen.
The metals or metal clusters present in metalloproteins, such as haemoglobins, transferrins, cytochromes, nitrogenases and hydrogenases are bound to nitrogen, sulphur or oxygen atoms belonging to protein residues.
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Based on reported structures, a focused library of biarylmethyl bound to the nitrogen atom of spiropiperidine was designed.
And the C in the rings directly bound to the nitrogen atoms of the pyridine unit at the high binding energy (red line in Figure 4a) [16].
Structure activity relationships (SARs) provide suggestions that, a methoxy group, bound to the nitrogen atom is important for activity (e.g., as in compounds 22, 24 and 25).
Both complexes have a pseudo-tetrahedral geometry: in 1 ruthenium is bound to the nitrogen, to the η6-coordinated p-cymene molecule and to two chloride ligands.
The known 1H spectrum of pyrrole carboxylic acid (from Sigma-Aldrich website) shows the proton that is bound to the nitrogen to have a wide peak at 11.7 ppm.
During the etching process, the APTES-doped silica also became densely covered with (1 2 nm) Au nanoparticles, bound to the nitrogen of the amine group of the APTES.
On the other hand, the methylpiperidine moiety is bound to the nitrogen of the indole, and the ion at m/ z 98 is observed as the base peak (Fig. 3d).
For example, a definition of a primary amine can be given by a SMARTS expression [N H2v3][ 6;!$(C=[O,S,N,P])] which requires that two hydrogen atoms are connected to a three-valent nitrogen atom connected to two hydrogens and a carbon atom that shall not be bound to oxygen, sulfur, nitrogen or phosphorous with a double bond.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com