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Secondly, the shape of the curve bears a strong relationship to both the pyrolysis coefficient (R/Avhv0.5) and the opening factor FO2. Thirdly, contrary to a number of other fire modelling curves, BFD curve does not need the use of time shifts.
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However, in the thermal wave pyrolysis regime (Bi>10) shrinkage affects both the pyrolysis time and the pyrolysis products.
Shrinkage affects both the pyrolysis time and the product yield in thermally thick regime.
During the calibration phase, the pyrolysis model coefficients are determined by comparisons with reference experimental data, for instance data taken from thermo-gravimetric and/or bench-scale experiments.
For the natural jarosite clay and ferric sulfate hydrate experiments, individual samples (i.e., samples run at one temperature step only, rather than using stepped pyrolysis) were run at 100°C intervals, the lowest at 400°C and the highest at 1000°C, allowing both the products of pyrolysis and the variation in decomposition rate at different temperatures to be investigated.
For each of the other minerals being studied, two individual experiments were carried out, one at 600°C and one at 1000°C to show the decomposition characteristics at both typical pyrolysis temperatures and at the higher temperature to identify any species released under the full range of pyrolysis conditions.
Note that both the basis sinusoids and their coefficients of projection are complex valued in general.
Meanwhile, the coke content of HZSM-5 was increased in both lignin and yellow poplar pyrolysis by replacing the pyrolysis atmosphere of nitrogen with methane.
It should be noted that the presence of inorganic compounds in the algal biomass in relatively large quantities may provide a certain catalytic effect on the thermal degradation processes (both in inert and oxidizing atmosphere), thus reducing the pyrolysis temperature.
The pyrolysis produces either whiskers, soot or both.
The most significant result demonstrated a significant effect of the pyrolysis temperature on the photocatalytic performance of both materials.
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