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Proteins are dynamic entities, with significant motions of both the main chain and side chains.
The extension is anchored to the β-sandwich at each end via a salt bridge interaction involving the side chains of Asp45 and Arg110 and hydrogen bonds between both the main chain carbonyl of Arg39 and Glu38Oε1 and Arg64Nη1.
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According to 13C NMR spectra, polar units were located both on the main chain and at the chain end.
When the diphenylanthracene fluorophores exist either both in the main chain and the side chain or only in the side chain, the polyesters reveal photoluminescence over a broad range of wavelength from 400 to about 700 nm with the maximum emitting intensity at about 450 nm.
The structural comparison with the recently published 3.5 Å model shows major discrepancies, both in the main chain tracing and in the side chain assignment of the two terminal domains R1 and R2.
In the C-terminal RRM domain, hydrogen bonds are formed between the side chain amide of Gln264 and both the main-chain oxygen and side-chain hydroxyl of Ser268 of the other subunit.
A new perfluoropolyether lubricant (LUB-A) with a 3-phenylpropyl functional group at both ends of the main chain was designed and synthesized by the authors for use in hard disk media, and its tribological performance was evaluated.
Two additional corner-sharing [TiO6] octahedra are condensed at both ends of the main chain.
New, wholly aromatic polyesters carrying 9,10-diphenylanthracene fluorophores along the main chain or both in the pendent and main chain were prepared and their properties were studied by differential scanning calorimetry, wide-angle X-ray diffractometry and fluorometry in solution as well as in thin solid films.
Amphiphilic type refers to the surface of functionalized iron oxide NPs containing both hydrophilic and hydrophobic chemical groups, the main chain of these functionalized small molecules or surfactants showed concurrence of hydrophobic and hydrophilic structural regions, which also will make the functionalized NPs possess both oil-solubility and water-solubility, such as sulfuric lycine.
Two additional [TiO6] octahedra (Ti2) are condensed onto the main chain at both ends of the zigzag chain through shared corners.
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