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As long as the perfluorinated proton exchange membrane (PEM) is used for the electrolyte, both the cell performance and life are highly dependent upon the water content in the electrolyte.
To assess the suitability of flow fields, a power-based efficiency, which takes account of both the cell performance and pumping power, is defined and calculated for different flow fields at different electrolyte flow rates.
In view of this fact, there exists a need to improve conventional DMFC system designs, including membrane electrode assemblies and the subsystems for supplying/removing reactants/products, so that both the cell performance and the specific energy can be simultaneously maximized.
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Parametric study on the cell performance was also performed.
A three-dimensional model was used to compare the cell performance for both designs.
Temperature plays a larger role in air-breathing fuel cell performance than the actual size of the cell, whereas both cell temperature and size influence the cell performance for forced convection fuel cells.
The effects of the cathode reactant inlet velocity and cathode reactant inlet relative humidity on the cell performance for both designs were also investigated.
For lower operating voltages, as the cathode reactant inlet velocity increases and the cathode reactant inlet relative humidity decreases, the cell performance for both designs improves.
The effects of microstructure, thickness and temperature of air electrode on the cell performance in both solid oxide electrolysis cell (SOEC) and solid oxide fuel cell (SOFC) are individually discussed.
A theoretical model is developed to simulate the species transport in both anode and cathode streams and the cell performance is analyzed accordingly by examining the effects of flow rate, concentration, and the geometric size of the system.
It is expected that, due to the water management problem, the effects of inlet humidity of reactant fuel gases on both anode and cathode sides on the cell performance are considerable.
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