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This paper studies complexation behaviour between block ionomers with metal sulfonate groups and pyridine-group-containing copolymers, i.e. poly styrene-co-4-vinyl poly styrene-co-4-vinylly(methyl methacrylate-co-4-vinyl poly styrene-co-4-vinyl solution and bulk.
The ionic interaction complexation between metal carboxylated polystyrene ionomers and poly(butyl methacrylate-co-vinyl pyridine) (BVP) in both solution and bulk was studied by viscometry, laser light scattering (LLS) and differential scanning calorimetry (DSC) and compared with that between BVP and carboxylated polystyrene (CPS), in which the interacting groups are in acid form.
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The zinc alkoxide complex prepared in situ from the reaction of (BDI Zn(N(SiMe3)2) (BDI = 2-((2,6-diisopropylphenyl)amido -4-((2,6-diisopropylphenyl)imino)-2-pentene) with ROH (R = iPr or Bn = CH2Ph) is amido -4-ent catalyst for both the solution and bulk ring-opening polymerization (ROP) of racemic-β-butyrolactone (BBL).
The optical properties of the fabricated nanostructures are comparable to those of solution and bulk materials.
The complex derived from the racemic-aminodiol ligand gave partially heterotactic polylactide in ROP of rac-lactide and afforded atactic polylactide in the bulk, whereas all other complexes yielded atactic polylactides both in solution and in bulk.
We successfully immobilized azide-tagged IFN-γ under a wide variety of reaction conditions, both in solution and to bulk hydrogels.
The fixed parameters were bulk solution density and bulk solution viscosity, which were assumed as 1000 kg/m and 0.001 kg/ms, respectively.
Cyclic voltammetric studies of the influence of surface chemistry on the electrochemical behaviour of granulated and powdered activated carbon samples in the presence of lead II) ions both in bulk solution and pre-adsorbed on carbon were carried out.
If the channel presents a vestibule at the pore access, and chloride is the major mobile anion which can access the vestibule, a Donnan equilibrium ensues between the vestibule and bulk solution (both intra- and extracellularly).
In the work reported herein, the kinetics of calcium carbonate scale formation is studied both in the bulk solution and on a metal surface.
In this paper, calcareous scale formation was studied both in the bulk solution and on the metal surface in three supersaturated scale formation solutions which represent typical waters encountered in oil and gas production.
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