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Because 3DA is located at the primer terminus where the 3′-OH attacks the α-phosphorus atom of the incoming dNTP, perturbing the minor groove hydrogen bonding would be expected to have a greater impact on catalysis than the situation in which disruption of the minor groove HB network affects the templating base.
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A2E, being composed of conjugated double bonds, would be expected to be stained by osmium tetroxide and appear electron dense.
If this H-bond is a critical determinant of the rate of slow inactivation, predicted outcomes are that strengthening the interaction should decelerate inactivation, while weakening the putative H-bond would be expected to increase the rate of inactivation.
The application of EDTA reduces the Ca ions available on the surface of the canal walls; therefore, the potential chemical bonding that would be expected with self-adhesive resin cements is compromised affecting the final bond strength.
The molecule contains sulfur-fluor bonds that would be expected to absorb heat.
This specific feature indicated formation of stable and/or long β-strands and strong hydrogen bonds, as would be expected for a stable fibrillar structure [53].
But even in the bond markets, banks would be expected to identify the (relatively few) private investors, so as to ensure that the tax applies to them as well.
Nearest neighbor Fe-O distances in the fully oxidized state match well to expected values for similarly coordinated solids, but reduction does not result in an extension of the Fe-O bond length, as would be expected from comparisons to the solid phase.
Core inflation has risen 0.9percentt since last October, according to the report, and a new bond-buying effort would be expected to raise prices further.
Dispersion effects are responsible for mediating nonbonded interactions such as hydrogen bonds and van der Waals "bonds" and therefore it would be expected that these would be important in this particular case.
The molecules are not hydrogen bonded within the structure (as would be expected from the available functional groups) and so the packing is dominated by van der Waals forces.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com