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To facilitate the design of laser host materials with optimized emission properties, detailed structural information at the atomic level is essential, regarding the local bonding environment of the active ions (distribution over distinct lattice sites) and their extent of local clustering as well as their population distribution over separate micro- or nanophases.
We also studied the average bonding environment of the material by XPS.
The transition of5D0 to7F2 is an electric dipole-allowed transition and is hypersensitive to the variation in the bonding environment of the Eu3+ ions.
Considering the fact that a model aqueous complex is being compared to a mineral, the level of agreement is remarkable and suggests that the bonding environment of the uranyl-phosphate complex is being modeled accurately.
Further information on the bonding environment of the uranium can be determined from analysis of the EXAFS spectra and their Fourier transform.
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The treated surfaces have been investigated by contact angle and atomic force microscopy measurements; X-ray photoelectron spectroscopy has been used to determine the surface composition and to get insight into the bonding environments of the treated surfaces.
It is not possible to identify unambiguously the bonding environments of the Hg II)–S -II) S -IIespeciesver, it is possible to say thowevery of the fitted bond lengths were isconsistent with homogeneous possibleatoon of β-Hgsaywhich suggesthathat Hg(II) was associated with the FeS surface in somanyay.
The results of this study both provide a new mechanistic understanding of uranium incorporation into hematite and define the nature of the bonding environment of uranium within the mineral structure.
The nature of the bonding environment of citrate ions within the layers were studied referring to shifts of hydroxyl and carbonyl peaks of citrate ions in FTIR spectra (Fig. 3).
On the other hand, the decomposition peak does not appear to be sharp for SEC-LDH but is a broad peak in the range of 200 450 °C, thus indicating the different bonding environment of curcuminoids after the intercalation.
The combined use of Raman and X-ray photoelectron spectroscopy allowed us to provide the first insight into the bonding environment of P incorporated into the carbon lattice, avoiding competing signals arising from synthesis byproducts.
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