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The binuclear unit are further linked by hydrogen bond to form a 2D wave-like supramolecular architecture.
The tetrabromocuprate and N, N'-bi-n-butyl-4,4′-bipyridiniums are held together via non-classical CH ⋯ Br hydrogen bond to form a 3-D hybrid structure.
In our approach, each telomerase-aided DNA sequence extension could trigger the formation of a long double-stranded DNA (dsDNA), making numerous AgNPs assembling along with this long strand through specific Ag S bond, to form a primary amplification element.
The reduction of the substrates proceeded via one-electron cleavage of the carbon bromine bond to form a radical-type intermediate that undergoes cyclization to afford the tetrahydrofuran structures in good yields.
The results obtained indicate that the reaction proceeds via cleavage of the carbon bromine bond to form a radical-type intermediate that undergoes cyclisation on the unsaturated C C bond to afford substituted tetrahydrofurans.
In compound I, molecules at (x, y, z) and (x + 1/2, −y − 1/2, z + 1/2) are linked through intermolecular C20-H20…O1 hydrogen bond to form a C8 zig-zag chain (Figure 2) running along 101 direction [21].
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For example, ozone in the atmosphere adds quickly to a double bond to form an unstable product that spontaneously decomposes.
As the water forms ice crystals and the glucomannan chains become more crowded in the remaining liquid, their coils overlap and bond to form an interconnected network.
The coal ions penetrate the surface and bond to form an amorphous, diamond-like coating less than 100 nanometres thick.
The cyanine boranyl radical pair may undergo back electron transfer to regenerate the substrate or undergo cleavage of a carbon boron bond to form an alkyl radical and triphenylboron.
We recognized that this state in fact might be expected to react with C2H2 to form C2H2D2 through the idealized mechanism involving terminalization of an [Fe D Fe] bridge of E4, and migratory insertion of bound C2H2 into the Fe D bond to form an Fe-alkenyl intermediate, followed by reductive elimination of C2H2D2.
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