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In this process, the molecules of 1 and 2 were broken into smaller pieces by cleavage of the N=N bond linking the two triazole rings and opening of their triazole rings.
Sixteen interaction modes involve a single hydrogen bond linking the two units.
While numerous low-abundance fragments can be detected in each case, the two most prominent fragments consistently correspond to the dissociation of the external disulfide bond linking the two monomeric units.
The single bond linking the two orthogonal units (C6-C20) is weakly conjugated with a C-C bond length of 1.497 3) Å. Crystals grown by method ii) gave the conformer represented by 13 b.
A radical mechanism for repair of SP by SPL was proposed by Mehl and Begley in 1999, where they proposed that an H-atom abstraction from C6 of SP could promote a radical-mediated β-scission to cleave the C C bond linking the two thymines.
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This pH-induced conformational change disrupts the chain of hydrogen bonds linking the two protomers.
Covalent bonds linking the two anti-parallel strands of DNA are extremely toxic, as they prevent DNA unwinding required for DNA replication and transcription.
These adducts create covalent bonds linking the two DNA strands in a duplex, generating an abnormal structure that poses a physical obstacle to the progression of cellular machinery like DNA replisomes [1,2].
(c) The bead is positioned immediately next to the nanomembrane and a bond forms, linking the two materials.
The β-ionone ring at the other end of the retinal is ensconced in a hydrophobic pocket formed by aromatic side chains, and the conjugated double-bond system linking the two is tightly engaged by a constriction in the retinal binding site which forces a negative 6-s cis twist of the β-ionone ring about the C6 C7 single bond and a twist about the C11=C12 double bond.
There is some ineffable bond linking these three characters, but no one asks questions, and no one provides answers unbidden.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com