Sentence examples for bond at the position from inspiring English sources

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Exact(3)

This reaction forms an ester bond at the C2' position of paclitaxel.

In addition the ozonolysis experiments show that the C18 acyl group has a double bond at the position shown, but it does not establish whether it is cis or trans.

Both enzymes catalyze the same kind of reaction, cleaving the C-C bond at the C-3' position forming the furanocoumarin skeleton and acetone in equimolar amounts [ 15, 16].

Similar(57)

Anecortave acetate differs in structure from cortisol by the removal of 11-beta hydroxyl, addition of a double bond at the C9-11 position, and addition of an acetate group at the C21 position to enhance bioavailability.

This elimination would create a double bond at the C2 C3 position of the glucosamine, which further set the stage for the elimination (peeling) at the C-4 position as the C-2 -NH- group gets deprotonated at basic conditions (Scheme 2A).

This iron-dependent enzyme catalyzes the insertion of a cis double bond at the Δ9 position of fatty acyl-CoAs with NADPH as a cofactor [13].

Our observation of reduced PlsEtns (containing the signature vinyl-ether bond at the SN1 position), but not their diacy counterparts, is also intriguing for several reasons.

CtFAD2-11 is a tri-functional enzyme able to introduce a carbon double bond in either cis or trans configuration, or a carbon triple (acetylenic) bond at the Δ12 position.

In this proposed model, the enzyme FaFAD1 would catalyze the conversion of oleic acid (18 1) to linoleic acid (18 2) by the introduction of a double bond at the Δ12 position, as performed by other FAD2 enzymes.

This gene encodes for a protein, FaFAD1, with extensive similarity to delta-twelve fatty acid desaturases, enzymes that catalyze the regioselective introduction of a double bond at the Δ12 position during lipid biosynthesis [ 34].

The vinyl-ether bond at the SN1 position is required for the lipid's anti-oxidant role and its effect on membrane fluidity, which is relevant to neuronal impairment because it affects vesicular fusion (for review see [ 49, 50]).

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