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Chemical bond approach is applied to analyze and explain the obtained glass properties.
The "through bond" approach has been recently developed to increase the interaction between the mobile π and localized d electrons in multifunctional molecular materials involving tetrathiafulvalene-based ligands.
The evidence indicates that the I.N.S. raised concerns about this blanket "no bond" approach, particularly when it became clear that the F.B.I.'s clearance process was slow and the I.N.S. had little information in many individual cases on which to base its continued opposition to bond.
The rate of production of fine material in the batch mode of grinding operation forms the basis for determination of the grindability parameter of the Bond approach and the breakage distribution function of the population balance model (PBM) approach to the mill scale-up design.
The immediate criticism of this student-teacher bond approach is its supposed lack of standards--no test scores, etc. to measure its overall effectiveness.
Other ab initio QM/MM methods, using a valence bond approach, have also been developed.
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All these H-abstraction processes can be divided into two parts: CH bond approaching to catalyst and subsequent breaking via a cross-point structure.
Generally, the H-abstraction reactivity increase when a catalyst has small LUMOcatalyst-HOMOsubstrate gap, CH bond approaching energy and distortion energy required to achieve its transition state (TS) geometry, and large electron affinity.
In order to guarantee the earnings of investors, however, bonds may be noncallable for a specified period, perhaps for five or 10 years, and their redemption price may be made equal to the face amount plus a "premium" amount that declines as the bond approaches its maturity date.
Somewhat common is a step-up structure, in which the coupon rises as the bond approaches maturity.
8 For instance in N1 and A1 (Scheme 1), Te⋅⋅⋅Te distances of around 3.3 Å are observed in the solid state (ca. 0.7 Å below the sum of the vdW radii), and Wiberg bond indices 9 (WBIs, a measure for the covalent character of a bond, approaching WBI=1 for a true single bond) of around 0.15 have been computed.
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