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For the sample MCS 10, blocking of micropores by Fe3O4 nanoparticles is observed.
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At higher coke contents (>2.6wt%), blocking of the micropores occurs.
From the results, it was shown the blocking of the micropores on the surface of ACF by treatment of Fe compound and Ti source.
These values are three orders of magnitude smaller than that of previous data measured in commercial extrudates due to partial blocking of the micropores of the zeolite with one of the materials used in the monolith preparation.
As can be observed in Fig. 10, showing TEM images of spent USY-A, it is likely that the catalytic coke components were essentially formed and trapped within the channels of the catalyst micropores, so the first direct effect on the active sites was either by poisoning or by blocking of access to reactant molecules.
It is possible that by metal particles blocking the micropores of the zeolite access to stronger acid sites are restricted.
In this work, we demonstrate a new perspective to circumvent the problem through blocking the micropores of carbon black by the in-situ formed TiO2 nano/sub-nano particles.
Some could have been expected according to the function of the surfactant, which is to block the micropores within the clay mineral structures, responsible for the swelling.
Furthermore, if phosphorus is located in the micropores of a zeolite, it can either favourably alter its shape-selective effects or block the micropores and reduce the overall accessibility of the zeolite material.
The Au-C and Au-M have significantly lower SSA than Au-Y confirming that the big gold particles formed in these samples blocked some of the micropores of zeolites.
In this way, the large cavities and small windows of H-SAPO-34 allow the formation and growth of aromatic species in the outer layers of the material but not their molecular transport inwards, which is going to block the micropore structure of the material.
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