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The results concerning the cases of the blocking electrode and the electrode with faradaic reaction are discussed from the theoretical point of view for a disk electrode.
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It was found that the semicircle in the high frequency range and the straight line in the low frequency range depend upon different blocking electrodes and polarization potentials applied in the experiments.
The analysis starts with the case characterized by perfect blocking electrodes and proceeds by considering non-blocking conditions on electrodes surface.
In the latter case, the EHD behaviour was similar to that of a flat, partially blocked electrode, and allowed an in situ evaluation of the average active site dimension.
Calculated electrochemical impedance of blocking electrode shows the lumped constant region in low frequency range and the distributed constant region in low frequency range.
This work proposes to add to an electrostatic filter an auxiliary blocking electrode, charged by the same charge as the particles.
The effect of the blocking electrode is to increase the collection efficiency of the electrostatic filter.
Moreover, the equivalent circuit also can be used to explain the impedance properties of Pt and stainless steel (SS) blocking electrodes both in the high and the low frequency ranges.
A mathematical model was developed to account for the effect of the blocking electrode.
n-Type conductivity of the commercial 7.5 m/o MSZ and 15 m/o CSZ electrolytes has been measured at oxygen pressures of the Ni(s -NiO s) mixture in the range 1073–1423 K by the blocking electrode technique.
At low frequency region, the spikes are attributed to temperature effect on the blocking electrode.
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