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After the separation step the blend components were precisely detected by an on-line capillary viscometer.
The blend components were synthesized by the reaction of polyamic acid with varying concentrations of a crosslinker (here antimony pentachloride or APC) as high as 1.67×10−2 mole/dm3 (i.e. hypothetically calculated Critical Crosslinker Concentration) up to lowest of 1.67×10−6 mole/dm3.
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The proton spin lattice relaxation experiments in the rotating frame on blended membranes indicated that independently of the preparation conditions, the blend components are not completely miscible possibly due to a weak polymer protein interaction.
All blend components are based on single-site catalysts.
Evidence for significant hydrogen bonding between the blend components was found from FTi.r.r
These findings indicate that blend components are placed in intimate contact as a result of the UPy UPy interactions.
The affinity of the compatibilizer with the blend components is therefore critically important for the effective compatibilization of immiscible polymer blends.
The investigations of the isotherms of the storage and loss moduli of the blends show that individual relaxation of the blend components is observed to a certain degree.
It is demonstrated that existing relations between the volume fraction at phase inversion and the viscosity ratio of the blend components are not generally valid.
A lack of good interaction between EVOH/PA blend components was further supported by the negative deviation from the simple additive rule seen in the mechanical properties of these blends.
The region of LLPS is asymmetrically placed at the high HV side of the phase diagram and the extent of phase separation increases as the relative HV level between the blend components is increased.
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