Sentence examples for bite angle of the from inspiring English sources

The dihedral angle is closely related to the bite angle of the ligand metal complex (P metal P angle), which is known to influence the catalytic behaviour and stereoselectivity in many asymmetric transformations26,27.

In [(Ti{ O iPr}2{bisdiketonate)})2], μ2-O iPr groups would lead to a much more crowded coordination sphere at the titanium centers, owing to the larger bite angle of the β-diketonate groups than the oximate groups.

Furthermore, the bite angle of the ligand could affect the ratio of branched (383) to linear (384) products, with small-bite-angle ligands increasing the C1 C1′ separation and disfavoring 1,1′ reductive elimination.

Indeed, both structures show quite similar bond properties, except from the larger bite angle of the dppf ligand in 2, as reflected by a considerable flattening of the phosphorus to Fe Fe bond connection line (Table 1).

The transformation was sensitive to the bite angle of the ligand and required an electron-deficient styrene additive, which has been demonstrated by Knochel to accelerate reductive elimination over β-hydride elimination.

The high reactivity of neutral [Rh(X)(dcpm)] fragments likely arises from the electron-rich character of the complex, and small bite angle of the diphosphine, which promotes oxidative addition.

A quantitative analysis of structural relationships among torsion angles, donor atom distances, and bite angles of the ligand systems and resulting metal complexes is presented.

The small bite angle of dcpm is crucial for lowering the barrier of this step and providing excellent reactivity with a variety of aldehydes.

Dependency of design force, design torque and maximum bite angle of a rolling mill on the reduction ratio models were fully considered in the draft schedule scheme.

Consideration of stress and bite force data, suggests that there is an optimal bite angle of between 25° and 35° in C. l. dingo.

Stress data, combined with bite force information, suggested that there is an optimal bite angle of between 25° and 35° in C. l. dingo.