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The only complex isolated is the bis complex (Et4N [Co(PyPSMe 2] (1) in which the potentially pentadentate PyPSMe2− ligand acts as tridentate and all four thioether sulfurs remain as pendant groups.
Ferrozine forms a bis complex which is highly specific to the ferrous form of the ionic metal [17] and adsorbs light strongly at 562 nm. Figure 2(i) shows a linear plot of standard Fe2+ against absorbance for the determination of ferric iron concentrations.
In bioimpedance spectroscopy (BIS), complex impedance is measured over a wide range of frequencies and the data are fit to a well-known model of biological tissue.
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Most researchers consider that alizarin and purpurin form bis complexes, ML2, with bidentate bonding of the ligand through one keto group of the quinone structure and the adjacent hydroxyl group at position 1 but others have suggested that the first metal ion attaches through hydroxyl groups at positions 1 and 2 (Fig. 6).
Also, the TiO2-DZ-Bi complex was analyzed by UV-visible diffuse reflectance spectra by collecting the material from Whatmann filter.
The bidentate ligand ethylenediamine forms a chelate bis-complex with copper II), having an overall formation constant β2 = 1020.6 M2 [1020.6
The overall stability constants for Fe(II) and Fe(III)-cys refers to the bis-complexes, n = 2.
In spite of the relatively long peptide loop, bis-complexes are also formed with the metal ion under basic conditions.
A dramatic result of numerous bi-complex duplications could be a duplication of a whole complex.
What evolutionary route would lead to the emergence of bi-complex paralogs?
Instead, we observed a statistical under-representation of bi-complex paralogs.
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