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The adjusted binary parameters from the data of binary pairs (carbon dioxide + n-decane) and (carbon dioxide + n-tetradecane) were used to correlate the generated ternary data.
The calculated ternary compositions were found to be in good agreement with the experimental data using the binary parameters from the data of binary pairs for both EOSs.
The generated ternary data were correlated with the adjusted binary parameters from the data of binary pairs (CO2 + decane) and (CO2 + tetradecane).
Having the binary parameters from the binary systems, the model was applied in a predictive way (i.e. no parameters were adjusted to data on ternary and multicomponent mixtures) to model the phase behaviour of ternary and quaternary systems with CO2 and glycols.
The database was constructed by the CALPHAD method where the binary parameters from the BaO-CaO and CaO-YO1.5 systems were presently optimized, those from the BaO-YO1.5 system were simulated by our previous assessments, and only limited amount of ternary parameters were introduced.
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The binary parameters for the other pairs are taken directly from the literature.
L 2, i j k ) where L ϑ, i j are the binary interaction parameters from the binary systems and L θ, i j k (θ = 0, 1, 2 ) are the ternary interaction parameters which are all modeled in power series of T. Several thermodynamic studies of the bulk Sn Ag Cu ternary system have been published [22 24].
With the binary parameters obtained from binary data, the equation has been satisfactorily used to predict the surface tension of ternary and quaternary systems.
Pure substance parameters of the Peng Robinson EOS are taken from the literature, whereas the binary parameters of the Van der Waals one-fluid mixing rule are adjusted to experimental binary VLE data.
We investigate vapor liquid equilibria (VLE) for polymer/solvent systems using the same model binary parameters obtained from liquid liquid equilibria (LLE) calculations.
The missing parameters of NRTL and UNIQUAC (for instance, acetone and OAL binary parameters) were estimated from UNIFAC.
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