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Binary interdiffusion coefficients are reported for aqueous HCl, HNO3 and H2SO4 at 25°C in columns of Amberlite IR-120(H) polystyrenesulfonic acid cation exchange resin beads.
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Interdiffusion coefficients are estimated by analysing the measured diffusion profiles.
Interdiffusion coefficients are evaluated at the intersection points of two independent diffusion paths sharing a common composition.
The data obtained suggest additionally that the interdiffusion coefficients are dependent on molecular weight.
First, interdiffusion coefficients are determined using Ni/NiAl diffusion couples forming a Ni3Al phase at the interface.
The results indicate that the interdiffusion coefficients are different, depending on the substrate steel grade; the interdiffusion coefficient is more stable when the steel substrate contains Cr and Mo.
The interdiffusion coefficients are retrieved from common compositions of two diffusion couples, which are then combined with thermodynamic descriptions to explore atomic mobilities of Cu, Cr and Ni in fcc Cu Cr Ni alloys within the CALPHAD framework.
Such main and cross interdiffusion coefficients are then used to inversely retrieve atomic mobilities of Co, Cr and Ni in fcc Co Cr Ni alloys, with the aid of available thermodynamic description.
Such main and cross interdiffusion coefficients are then used to inversely retrieve atomic mobilities of Cu, Fe and Co in fcc Cu Fe Co alloys, with the aid of available thermodynamic description.
The diffusion couples were annealed at temperatures from 493 to 848 K and the interdiffusion coefficients were determined from the concentration profiles using the Boltzmann Matano technique.
The experimental interdiffusion coefficients were critically assessed to obtain the atomic mobilities of Co, Mo and W in fcc Co Mo W alloys by using the DICTRA (Diffusion-Controlled TRAnsformations) software package.
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