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Also, the corresponding binary interaction parameters were regressed.
Initially, new binary interaction parameters were estimated for (CO2 + glycol) binary mixtures.
To construct the theoretical phase diagrams, all binary interaction parameters were determined accurately and thoroughly revisited.
The binary interaction parameters were adjusted, and the volume translation technique was employed to correlate the experimental compositions and densities.
The NRTL binary interaction parameters were estimated from the experimental data of the two-component vapor liquid equilibrium.
To improve the predictions, the binary interaction parameters were adjusted and the volume translation technique was applied.
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It is shown that three binary interaction parameters are sufficient to correlate each binary system.
Binary interaction parameters are calculated from experimental PTxy data and generalized correlations are proposed.
The increased miscibility is quantitatively predicted by the modified theory when binary interaction parameters are calculated by group contribution methods.
The comparison reveals that on average the most accurate VLE and density predictions are obtained with the SAFT-based EoSs, while similar results in VLE calculations are obtained with the four EoSs when regressed binary interaction parameters are used.
The E-PPR78 model is a predictive version of the widely used Peng Robinson equation of state in which the binary interaction parameters are estimated by a group-contribution method.
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