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With micro-genetic algorithm, the binary interaction parameters of UNIQUAC model were estimated.
Subsequently, the corresponding binary interaction parameters of each model were obtained.
The binary interaction parameters of both models have been obtained by simplex method.
Table 3 collects the binary interaction parameters of components, which are used to calculate the activity coefficient of components by the electrolyte-NRTL model.
To obtain the model binary interaction parameters of the hyperbranched polymer + water the subsystem hyperbranched polymer + water was experimentally estimated, and for the subsystem PEG8000 water experimental data from literature were used, the parameters were fitted in both cases.
The binary interaction parameters of the model were estimated by correlating vapor-liquid equilibrium (VLE) data and, for some systems, successful predictions of the critical loci were obtained even when VLE data far from the critical point were used.
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The effect of gas injection on asphaltene precipitation is also correlated with experimental data by tuning a single binary interaction parameter of the injected gas component and asphaltene pair.
Built on the thermodynamic framework of symmetric electrolyte Non-Random Two Liquid (eNRTL) theory, the model correlates composition dependency of the solution nonideality with two binary interaction parameters for each of the molecule-electrolyte pairs and the electrolyte-electrolyte pairs present in the system.
Instead of developing a very detailed model, the objective of the model is to attain a fixed set of binary interaction parameters for a given OSN membrane, solvents and solutes in analogy to vapour liquid equilibria (VLE) parameter sets.
Popular methods in CAMxD require the use of binary interaction parameters to calculate mixture thermodynamics, and this necessity places inherent limitations on the possible chemical search space.
Solubility data are well represented with nonclassical mixing rules and temperature-dependent binary interaction parameters for all the cubic equations of state used.
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