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Beyond a catalyst concentration of 1.5 wt%, the biodiesel yield decreased due to incomplete reaction and soap formation.
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The catalyst PL with its maximum shifted slightly to around 600 nm appears, whereas the PVK luminescence with its maximum at about 410 nm vanishes almost completely once a catalyst concentration of 0.56 ±0.02) mg mL−2 is reached (curve with circles).
All profiles were correlated as a catalysts concentration function.
The results indicated an increase in the soap formation with an increase in the catalyst concentration.
For this base pair, data at low concentrations of ammonia, which exhibited a linear relation between the ammonia catalyst concentration and kex, were fit to eq 3.
When the transition occurs, the increase in the catalyst concentration is accompanied by a sharp decrease in the activated monomer concentration.
Catalyst concentration, mol/l.
Active catalyst concentration, mol/l.
aIn all cases the catalyst concentration is 2.0 mM.
As there are many more activated monomers than catalysts, the activated monomer concentration varies more smoothly than the catalyst concentration.
Furthermore, doubling the substrate and catalyst concentrations allowed for a significant decrease in reaction time (Table 1, entry 6).
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