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According to the relation between the specific magnetization and NaOH content, the action of additional NaOH can be discussed further as follows.
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For a concentration of 6.288 mg/cc, the specific magnetization of the magnetic particles is 67emu/g.
Figure 1 shows the specific magnetization curves of the samples.
The specific magnetization of 67 emu/g for SPIONs is reasonably a good value and is sufficient for applications.
Clearly, the non-monotonic variation of the specific magnetization of the samples as a function of FeCl2 concentration can be attributed to the phase changes.
The study of specific magnetization of the nanocomposites vs. applied magnetic field indicates their ferromagnetic properties.
The values of specific magnetization at 10 kOe, remnant magnetization (M r), the ratio of remnant magnetization to bulk saturation magnetization (M r/M s), and coercive forces (H c) are also tabulated in Table 1.
At first, the magnetization strengthened as the FeCl2 concentration increased from 0.025 M to 0.100 M, then the magnetization weakened as the concentration increased from 0.100 M to 1.000 M. Figure 1 Specific magnetization curves for the samples.
Magnetization of samples (0) and (1) were nearly the same, that of sample (2) was the strongest, and the magnetization weakened gradually from samples (2) to sample (4). Figure 4 Specific magnetization curves of the samples prepared without NaOH (0) and with increasing NaOH concentrations: 0.35 (1), 0.70 (2), 1.40 (3) and 2.10 M (4).
The diameter of SmSMM-DHA microspheres was around 500 nm and the specific saturation magnetization was 61.25 emu g−1.
Moreover, vibrating sample magnetometer results manifest that these three composites possess the specific saturation magnetization of 33.7 emu/g, 27.2 emu/g and 23.0 emu/g, respectively.
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