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Bell-shape structure-activity relationship (SAR) was found between the initial rate for the catalysis of ascorbate oxidation, vo(Asc)ox and E1/2, identifying cationic Mn III) N-substituted pyridylporphyrins with E1/2>0 mV vs NHE as efficient catalysts for ascorbate oxidation.
The profound insight towards the suitability of the pseudo-second order was developed through the logarithmic plot extrapolated between the initial rate constant (h, mg−1g−1min−1) and the initial concentration (mg/L) of metal ions: h = 0.719,C_{text{o}} - 1.471quad R^{2} = 0.999quad {text{for}};{text{Cu}} (14) h = 0.757,C_{text{o}} - 1.588quad R^{2} = 0.999quad {text{for}};{text{Zn}}. (15).
Figure 3 presents the relationship between the initial rate of polymerization and concentration of photoinitiator.
Furthermore, no significant difference was found between the initial rate of whole cells and pelleted cell debris.
The scaling of the magnitude of postural responses generated using somatosensory feedback was quantified by analyzing the correlation between the initial rate of change of torque, the integrated EMG, and the translation velocity during unexpected perturbations.
The relationship between the initial rate of the reaction and substrate concentration (1-2000 μM) was determined using the Michaelis-Menten equation and a non-linear regression program (Enzfitter, Elsevier Biosoft).
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Figure 4 shows the same relationship between the initial rates for each incubation from experiments A - D as a function of [Phe]o when normalized to a maximum rate determined for each respective experiment (R o /R max ) are combined (all conducted at 100 g/L pyrite loading).
Both rates are insensitive to the assumed time period for the initial rate between 30 and 90 days (Table 3).
Although the expression of SpARC1 varied considerably between embryo batches (Fig. 7B), the initial rate of NAADP production, which was linear over the first three hours (Fig. 7C), correlated well with the amount of protein detectable on Western blots (Fig. 7D).
Thus, it seems possible that in this in vivo cytotoxicity assay largely measures the initial rate of encounter between target cells and CD8 T cells, and hardly the rate of killing of targets.
The initial rate of production between 0 and 1.5 h would not be affected by the choice of reaction time for samples with slight curvature, but could be affected for highly curved samples (generally above 300 nM Fe(II), as shown in Figure S2) if curvature occurs very early.
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