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The current that flows between the indicator electrode and a second electrode in the solution is measured and related to the concentration of the analyte.
The potential between the indicator electrode and the reference electrode varies as the concentration or activity of that particular species varies.
The potential is controlled between the indicator electrode and the reference electrode, but the current flows between the auxiliary electrode and the indicator electrode.
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The analyte electrochemically reacts at the indicator electrode.
The working electrode corresponds to the indicator electrode in voltammetry and most other electroanalytical methods.
Figure 3: The potential ramps applied to the indicator electrode during selected forms of polarography and the corresponding polarograms.
The potential of the indicator electrode varies, depending on the concentration of the analyte, while the potential of the reference electrode is constant.
As the electrode potential is changed, however, sufficient energy is applied to the indicator electrode to cause the reaction to take place.
It can be divided into two categories on the basis of the nature of the indicator electrode.
The several forms of voltammetry differ in the type of varying potential that is applied to the indicator electrode.
Typically the potential is initially adjusted to a value at which no electrochemical reaction occurs at the indicator electrode.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com