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The trapped gases between the graphite layers expand in the synthesis process and detach the flakes from each other.
The results obtained evidenced two mechanisms for sodium insertion into graphite: sodium intercalation between the graphite layers and sodium sorption into the porosity of the material.
The interfacial mechanism is associated with the dynamic sliding at low amplitudes between the graphite layers in the cell wall of exfoliated graphite during dynamic loading in the elastic regime.
The ease of sliding is enabled by the loosening of the interlayer interface that has occurred during exfoliation, in which the cell wall extends greatly like a balloon due to extensive sliding between the graphite layers in the cell wall.
Moreover, the incompetent behaviors of the MWCNTs would become substantial as the number of graphite layers increases, and the deficient load transfer efficiency in the MWCNTs would not be modified effectively even though the chemical bonding between the graphite layers were constructed.
Hence, we speculate that Sn atoms diffuse preferentially in the space between the graphite layers.
Similar(48)
The lower coordination number between the Na+ ions and DME and the interaction between DME and the graphite layers are believed to be responsible for the structural stability of the co-intercalated graphite.
Results show that the variations of structural parameters and compositions of the weak layers cause significant changes in the volume fraction of graphite phase, spacing among the graphite layers and interfacial state between the two layers, thus affecting the formation of lubricating and transferring films, load-bearing capacities and wear mechanisms of the materials.
However, under solvothermal conditions, the oleylamine molecules readily intercalate into the graphite layers, which facilitates the exfoliation of graphite.
In order to further reveal the relationship between the thickness of the graphite layer and magnetic properties, the Co@C nanoparticles were grown at 400 °C for different times.
Moreover, it is found that higher membered carbon rings and defects in the graphite layer act as diffusion routes between disordered carbon layers.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com