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The relationship between the distribution coefficient, DM, and the concentration ratios of Cionophore,IL/Cmetal ion,aq were investigated.
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A simple linear relationship was observed between the distribution coefficients and the relative solubilities in the toluene+chloroform system.
A quantitative relationship between the distribution coefficients of uranium (VI) measured for the series of 7 extractants and two molecular descriptors has been developed.
When the distribution coefficient between the fluid and the solid phases is different for the two components, the elution profiles are broadened to an extent that depends upon the rate of reaction.
Finally, the current response of the different solvent systems is proportional to the distribution coefficient between the SLM and aqueous phase.
According to Schwarzenbach et al. (19), the distribution coefficient between particulate organic matter and water can be estimated with a linear free energy relationship based on the organochlorine compound's octanol−water partitioning coefficient KOW.
The distribution coefficient of furfural between the organic and aqueous phases was determined as follows: 50 mL furfural solution (2 wt.%) and 50 mL extraction agent were fed into a 150-mL separatory funnel, and the mixture was vigorously shaken at room temperature, then stood for 7 h.
The distribution coefficient (Kc) of DD between the solvent and IR matrix was also determined for scCO2 and toluene.
In this way, plutonium entering the water after a certain time is accumulated in the bottom sediment in quantities depending on the distribution coefficient of the radionuclide between the water phase and the sediment, including the subsequent chemical reactions such as complexation, coprecipitation, and radiocolloid formation.
The distribution coefficient and separation factor were used to investigate the distribution of cyclohexanol and cyclohexanone between water and cyclohexane.
The distribution coefficients of EP between crystal phase and solution phase were determined.
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