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It enabled one to obtain a dependence between the catalyst activity and the substrate concentration at the optimal conditions.
A simple dependence between the catalyst activity and the coke content on the catalyst (up to 17 wt% for significant time-on-stream) was tested.
For the first of these examples, a correlation between the catalyst activity and the standard electrode potential was used as the basis for predicting that gold would be the best catalyst for this reaction.
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Both contact modes between plasma and catalytic particles promoted the catalyst activity at low temperatures (e.g., 673 K).
A volcano-like relationship between the amount of oxygen vacancy and the catalyst activity is established.
Up to now, the catalyst activity and efficiency of cobalt catalyst are still not so high for CRPs (CMRP or ATRP).
The most attractive approach to reduce the catalyst residue in CRPs products is to substantially increase the catalyst activity so that only a very small amount of catalyst is needed to catalyze the polymerization.
Density functional theory (DFT) studies reproduced the catalyst activity order of the alkaline earth metal oxide catalysts found by the experiment.
Studies using a combination of atomic force microscopy and X-ray photoelectron spectroscopy revealed a general correlation between the catalyst behavior (activity and lifetime) and the 3D evolution of the catalyst for active catalysts (Al2O3/Fe and TiN/Fe).
Relationships were observed between (i) catalyst activity and the binding energy of Zr 3d5/2 electrons and (ii) Al/Zr ratio on silica and the average ethylene incorporation.
It was shown that the best compromise between catalyst activity and selectivity requires a low amount of oxygenated groups on the support surface of the final catalyst, typically less than 700 μmol/g CO + CO2 evolved during TPD experiments, together with an optimized platinum particle size ranging between 10 and 20 nm.
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CEO of Professional Science Editing for Scientists @ prosciediting.com