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In this work, TPO blends with different blend morphologies were prepared by controlling the viscosity ratio between the blending components.
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This was attributed to the promotion of specific polar interactions between the blend components.
Evidence for significant hydrogen bonding between the blend components was found from FTi.r.r
However, using Peak Force Tapping techniques (PFT-AFM) revealed peculiar morphologies upon the affinity and the interfacial compatibilization between the blend components.
During the melt-extrusion of blends of aliphatic polyamide 46 (PA 46) and aromatic polyamide 6I (PA 6I), transamidation reactions occur between the blend components.
It is likely that these observations are related to the interactions between the blend components which result in changes in the local molecular environment on blending.
Their fractal dimensions depend on the type of chemical interactions between the blend components resulting either in grafted or crosslinked interfaces.
Additionally, the presence of a wide and asymmetric enthalpic step, whose position follows Fox predictions, demonstrates miscibility between the blend components.
Specific interactions between the blend components (especially in crystalline/amorphous blends) induce miscibility under certain conditions However, depending on the processing history and the composition, the crystalline component crystallizes in different polymorphs.
It is likely that these observations are related to some interactions and a partial segmental mixing between the blend components, which result in changes in the local molecular environment on blending.
In summary, a lower viscosity ratio between the blend components, in which upon addition due to thermodynamic reasons the CNTs localize (here PC), and the other component (here SAN) is favorable for high electrical conductivity values.
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