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Finally, we analyze the correlation between the atomic mobility and the thermo-mechanical treatments in metallic glasses.
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Importantly, to analyze the atomic mobility in amorphous materials, a physical theory is introduced.
The atomic mobility parameters in liquid phase are theoretically calculated by the newly modified Sutherland equation, and the atomic mobility parameters in fcc phase are optimized by the diffusivities measured in the present work and from the literature.
On the other hand, the atomic mobility in metallic glass is enhanced by deformation (i.e. compression and cold rolling).
The diffusion database contains the atomic mobility parameters for different diffusing elements in liquid and fcc phase.
On the one hand, the atomic mobility in metallic glasses is reduced by physical aging or crystallization.
This marked difference with the AFM results can be understood in terms of 3D changes produced by the atomic mobility.
The results indicate that the atomic mobilities can reproduce the experiment data reasonably well.
The atomic mobilities obtained in this work are essential to guide the design of candidate Ag-based alloys.
However, in presence of real dependencies between atomic mobility, clustering achieves much more improvement.
In general the microstructural instability measured as the size of the reaction zone increased with the increase in composition difference between the two initial alloys and in atomic mobility difference between the diffusing species.
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