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Gradient structure significantly decreases hardness mismatch between the amorphous layer and the matrix of Mg alloy.
The results show that composite coatings exhibit an almost fully compact structure at interfaces between the amorphous layer and the NiCrAl layer with an attractive combination of high hardness and bonding strength, good interfacial toughness and high impact resistance with respect to the monolithic amorphous coating.
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The d.s.c. and SAXS studies of the blends lead to the conclusion that the PEI segments are incorporated in the amorphous layer between the stacked N-TPI crystals, regardless of the phase separation.
The enhancement of the bonding strength results from the formation of the localized metallurgical bonding as well as complete wettability between the NiCrAl layer and the amorphous layer, which is observed by high-temperature contact angle tests.
A transition in the plastic deformation mode takes place in the nanolaminated structure from the pure shear banding deformation in the amorphous CuZr to the interactive deformation between interfacial dislocation in the crystalline layer and shear transformation zones (STZs) in the amorphous layer.
Consequently, the stress intensity drops in the amorphous layer.
As a thin amorphous layer is located just beneath the tool edge, a local deformation (LD1) is initiated from the amorphous layer, as shown in Fig. 11a.
In addition, the subsurface damages beneath the machined surface are attenuated by the amorphous layer.
The chip is formed by extrusion independent of the amorphous layer thickness.
As the amorphous layer becomes thicker, the atomic shear is weakened, especially in region III.
The amorphous layer located at the trench bottom surface is constructed of gallium oxide.
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