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The key to success was design of a substrate, which directed the reaction mechanism through a selective pathway and use of a suitable catalyst combination to achieve the desired balance between reactivity and selectivity.
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We postulated that readily generated 4 might provide the right balance between kinetic reactivity and selectivity (Scheme 2).
The relationship between the structure of achiral biphenyl moiety and the reactivity and selectivity of 4 has been evaluated in the asymmetric alkylation of glycinate Schiff base 2 under typical phase-transfer conditions, leading to the identification of 4l as an optimal catalyst structure to exhibit an excellent enantiocontrol in the reactions with various alkyl halides.
Deuterium isotope (H/D) exchange between methane and water was used to examine the reaction reactivity and selectivity.
In the selective hydrogenation of the unsaturated aldehydes crotonaldehyde and acrolein an increased reactivity and selectivity to the desired alcohol was found with increasing silver nanoparticle size.
It is well known that H and CO coverage play essential roles in the reactivity and selectivity of FTS.
The results clearly demonstrate the better reactivity and selectivity of NBS/p-TsOH/CH3CN as a brominating mixture under microwave conditions.
Real catalysts mainly consist of a heterometallic or bimetallic system, which can enhance reactivity and selectivity [13].
The presence of CO2 decreases the reactivity and selectivity of potassium-containing sample.
The reactivity and selectivity of nanostructures are mostly based on the size and shape of the nanocrystals in catalytic reactions.
Heterogeneous rhenium catalysts were stable systems to be used for several runs without any appreciable reduction of reactivity and selectivity.
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CEO of Professional Science Editing for Scientists @ prosciediting.com