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A novel technique allowed EIS and microscopical observation of the interface between electrode and solution to be coupled in situ.
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Key drawbacks of electroporation include the need for an ion-free condition and the requirement of contact between electrodes and solution.
Membrane potentials were corrected for a liquid junction potential measured between electrode and bath solutions of –4 mV for the KCl intracellular solution or –10 mV for the K-aspartate solution.
All three types of HFBI-coated HOperformtrodelectronm electransfernsfer between the electrode and solution phase through the dense HFBI molecular layer.
The HFBI molecular carrier can easily form ordered structures; however, the dense molecular layers form an electrochemical barrier between the electrode and solution phase.
The interfacial phenomena between Cu electrode and solution of lithium perchlorate in ethylene carbonate (EC)–dimethyl carbonate (DMC) have been investigated using in situ reflection absorption Fourier transform infrared (FTIR) spectroscopy and single reflection ATR FTIR spectroscopy.
We also demonstrate that numerical models which do not include the charge transfer mechanism between electrodes and the buffer solution will fail to predict the reduction of these geometric effects with increased buffer conductivity.
The distance between electrode and electrolyte (cm).
However, some reactivity between positive electrodes and solutions has been observed below this potential.
The standard heterogeneous transfer rate constant was 0.1 cm s−1 and decreased, in the presence of oxygen, when the contact time between the electrode and the solution increased.
The arc for the very high-frequency range corresponded to the charge transfer limiting process and was ascribed to the double-layer capacitance in parallel with the charge transfer resistance (Rct) at the contact interface between the electrode and electrolyte solution [42].
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