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We found that the K1Mn10/Al2O3 catalyst exhibited the best CO oxidation activity with the TOF of 1.5 × 10−3 s−1 for 100% CO conversion at 260 °C, which is 50 °C lower than that on Mn/Al2O3 catalyst.
The best CO tolerant catalyst is, however, not the best catalyst in DMFC.
The best CO formation (32%) was obtained with Ti+H electrode at −2.2 V and −30°C.
Among them, the MnCoCe/M system presented the best CO conversion at low temperatures and the Co(I /CeO2-M catalyst, the best selectI /CeO2-Moward catalyst
In addition, the electrochemical CO-striping measurement reveals that the Pd/RuO2-SnO2/C catalyst exhibits the largest electrochemical active surface and the best CO tolerance.
The best CO tolerant catalyst is obtained by using a 12/1 ball-to-powder ratio and a 1 1 8 proportion profortion of dispersive agent.
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