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All the typical bands of DS were observed at corresponding wavenumbers, such as C H stretching and bending bands (2840 2955 cm−1), –OSO3 − anions stretching and bending bands (1211, 1060, and 720 cm−1) [21].
The mono-substituted aromatic ring of the 8-hydroxyquinoline ligand is shown by the bending bands at (709 and 796 cm−1).
The mechanisms of water diffusion into PHDDT films with different phase morphologies can be obtained through 2DIR analysis in OH stretching and bending bands.
Since thin films contains electronegative oxygen and nitrogen atoms, C O and C N (stretching) and N H (bending) bands are polarized, resulting in specific interactions occurring at the inter phase.
(a) Plot of the probability density for the electron under the flat band and bending band.
The absorption peaks 930, 848, and 704 cm−1 revealed the existence of aromatic C H bending band.
Zr-OH-group bending band vibration peaks appeared at 1,517 and 1,487 cm−1.
We performed a calculation of the exciton energy under the bending band following [17].
Electron and heavy-hole wavefunctions with their eigenenergies under the bending band are also plotted in Figure 2a.
Figure 3a plots the probability density of the electron under the flat band (ns = 0 cm-2) and the bending band (ns = 5 × 1011 cm-2).
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