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[FeNi5 CO 13]2− reacts readily with acids, to yield the already known [HFe3Ni(CO)12]− (3), and with CO, being stepwise fragmented to species of lower nuclearity, ending with [Fe3Ni(CO)12]2− (4) or [Fe2 CO 8]2−.
The G(i) in our plots are smooth (apart from being stepwise from one i to the next) even though all imax terms were estimated together, without any smoothing or constraint.
Similar(58)
The effective pressure was stepwise cyclically varied from 0 to 70 MPa at a constant pore pressure of 23 MPa.
Next, the sample size was stepwise reduced to find the minimal sample size necessary to identify a significant association.
Other reactions go in more than one step and are said to be stepwise, composite, or complex.
If a reaction is stepwise, kinetic measurements provide evidence for the mechanism of the individual elementary steps.
Subsequently, the carbonyl-group at C3 is stepwise reduced and dehydrated yielding a chain-elongated product.
These carbonyl species are stepwise converted to di- (∼2188 cm−1) and tricarbonyls (∼2180 cm−1).
The reaction is stepwise with a hydride transfer as the rate determining step.
This signal can also be stepwise reset by introduction of different competing substances.
The analytic approach was stepwise linear regression, with forward selection and p < 0.05 threshold for significance.
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