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The melting behaviour of the copolymers was studied by differential scanning calorimetry.
The particle coarsening had little or no effect on the crystallisation behaviour of the copolymers.
The surface behaviour of the copolymers has been studied as function of the side chain length.
The stress-strain behaviour of the copolymers and their blends was evaluated as a function of temperature.
The behaviour of the copolymers with NIPAAm/MALEU ratios 15:1 and 10 1 was investigated also between pH 3 and 11 in 0.1 M NaCl.
DMTA and DSC techniques showed a melting behaviour of the copolymers (Tm=174 175 °C; ΔHm=19 37 J/g) quite similar to that of PLLA.
Similar(51)
The thermal behaviour of the copolymer is characterized by a very broad melting and crystallization range.
The melting behaviour of the copolymer is strongly influenced by annealing, but these changes can be reversed by remelting.
The self-assembly behaviour of the copolymer in selective solvents was evaluated by SEM, and stable micelles with a diameter of 400 600 nm were observed when the copolymer content was approximately 0.2 wt.%.
The gelation behaviour of the copolymer solution showed that this polyether-ester polymer hydrogel still retained the characteristics of the thermo-sensitive Sol Gel transition, and the critical gelation concentration (CGC) decreased to 4 6%15%5% was achieved using only F127).
The swelling behaviour of the copolymer membranes showed that the lower content of NTBA gives discontinuous volume transition with respect to temperature whereas, the presence of higher amounts of NTBA showed decreased swelling ratios with very little influence of temperature on the swelling.
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