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Load dependent frictional behavior of these films was investigated in present study.
It is believed that this layer is solely responsible for the capacitive behavior of these films.
The electrochemical behavior of these films resembles the one observed for electrochemically synthesized polymers.
Investigating the tribological behavior of these films against steel ball is useful for implementing reliable micro-sliding based device applications.
Pin-on-disk friction tests were performed under vacuum to observe the friction and wear behavior of these films.
Such a large discrepancy in friction and wear behavior of these films could be explained in terms of microstructure and phase composition.
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The hydrolyzed behaviors of these films were examined by quartz cell microbalance, showing a slow degradation process.
This work demonstrates the excellent capacity rate performance as well as the efficient and homogeneous behavior of these oriented films can be explained by their specific microstructure.
The behavior of these composite films has been compared in terms of shifts in relaxation temperature (assessed by Dynamic Mechanical Analysis), in monomer composition (assessed by Nuclear Magnetic Resonance analysis) and in molecular weight (assessed by Gel Permeation Chromatography).
The mechanical properties and the tribological behavior of these thin films are related to the chemical composition and the microstructure of these advanced materials, characterized by electron microprobe analysis, Auger electron spectroscopy, X-ray photoelectron spectroscopy, X-ray diffraction, and high resolution transmission electron microscopy.
The electrical behavior of these POEGMA films was also studied to determine the potential impact on surrounding electronic devices, yielding information on relative permittivity and breakdown field for POEGMA in both dry and hydrated states.
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