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Different mechanisms can explain the catalytic behavior of these complexes.
The behavior of these complexes may provide a model for peptide editing by DM in endosomes.
Lastly, behavior of these complexes under conditions mimicking the endosomal environment (where the release of the cognate metal actually occurs) was also evaluated.
Self-aggregation behavior of these complexes was investigated, showing that the three synthesized AziRu derivatives able to form liposomes and, under specific conditions, elongated micelles.
The observation that the complexes can be characterized by their activation energy for thermal decomposition (which lies in the range 160 420 kJ mol−1) provides the basis for a stochastic description of the behavior of these complexes and their processes of formation and gasification.
The formation of bridging complexes between metal oxides and OM has been briefly discussed in the literature [20] but significant evidence of the occurrence and sorption behavior of these complexes in environmental systems is scare.
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Prediction of the crystallization behavior of these complex systems as a function of temperature can only be achieved using a thermodynamic model.
While challenges related to image resolution and contrast complicate the characterization in specific cases, non-destructive 3D imaging with μCT is shown to contribute to the understanding of the link between the microstructure and the self-healing behavior of these complex materials.
8 It is expected that over the coming years more insights will be obtained into the behavior of these complex nonlinear models through systematic mathematical analysis of the important emerging properties and that extended TMDD models will be developed that incorporate new biological processes to account for new emerging experimental data.
The mechanism of different behaviors of these complexes has been discussed.
Regarding the sucrose gradients, we believe that running our extracts on sucrose gradients would not be very informative: Gopalakrishnan et al. detect S-CAP complexes, and they analyze the behavior of these isolated complexes on sucrose gradients; in contrast, we do not detect S-CAP complexes, so cannot analyze their behavior on sucrose gradients.
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