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Correlations with experimental behavior of the catalysts were calculated by means of partial least square regression (PLS).
The copolymerization behavior of the catalysts and the influence of the polymerization temperature were investigated.
Under the same operating conditions, the behavior of the catalysts is quite different as the Ni catalyst promotes H2 production much more than the Ru catalyst.
It was shown that the sulfidation behavior of the catalysts prepared using the chelating agents depends on the drying condition: the lower drying temperature, the later DMDS conversion and oxide precursor sulfidation starts.
Analyses with H2-TPR were carried out to understand the reduction behavior of the catalysts.
Thus, time-on-stream study is very useful to understand the behavior of the catalysts.
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The effect of Co loading on aging behavior of the catalyst was also studied.
Models with different assumptions were examined, regarding the behavior of the catalyst, as deactivated, and its effect on the reactions of the lumping scheme.
A population balance model has been formulated to simulate the time-dependent behavior of the catalyst inventory of a fluidized-bed reactor/regenerator loop.
Then, a set of tests under the cyclic CH4-H2 feed switch mode over different time frames, followed by the TPO measurements of the spent samples, was performed to pursue the coke accumulation behavior of the catalyst over its lifetime.
It is possible to group the different mechanisms into three main families depending on the "role" and behavior of the catalyst: (i) Lewis acid base catalysis; (ii) CH activation (iii) insertion/β-elimination.
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behavior of the drivers
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