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This work was undertaken because the pore energy formulas existing in the literature predict qualitatively different behavior of large pores: the original formula proposed by Abidor et al. in 1979 implies that the electrical force expanding the pore increases linearly with pore radius, while later extensions of this formula imply that this force decreases to zero for large pores.
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Catalytic behavior of metal organic-frameworks (metal organic-frameworks(Fe) and MOFs100(Cu3 BTC 2nvestigated in p-xylene acylation with benzoyl chloride and compared with the behavior of large pore zeolites Beta and USY.
In addition, flow in fractured vuggy reservoirs may be further complicated by occurrence of non-Darcy's and other nonlinear flow behavior, because of large pore space and high-permeability flow channels.
The indicated great abundance of large pores hints on the large available pore space being involved in fluid migration.
Because of their rarity, the identity of large pores is less certain.
The existence of agglomerated MWNTs resulted in the formation of large pores.
The formation of large pores increased with increasing sintering temperature and MWNT content.
They postulated that the numerous small pores allowed the ready passage of small molecules and that the lesser number of large pores allowed limited extravasation of plasma proteins.
The as-prepared Co3O4-Al2O3 nanocomposites displayed distinct features of large pore volume and stable assembled morphology, and thus showed significant advantages in mass transfer and redox behavior.
Lefevre, B. et al. Synthesis of large-pore mesostructured micelle-templated silicas as discrete spheres.
These production parameters can be, naturally, controlled and scaffolds of larger pore size can be tailored upon need.
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