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Crystalline silicon nanostructures are commonly known to exhibit anisotropic expansion behavior during the lithiation that leads to grooving and fracture.
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AgLix alloy was formed during the lithiation.
Amorphous carbon could also promote the electron transfer during the lithiation and delithiation process.
Porous structures may accommodate the strain induced by the volume expansion during the lithiation process.
However, large volume expansion during the lithiation process limits their practical applications.
However, dramatic volume expansion during the lithiation of silicon complicates its practical implementation.
The peak at 0.16 V are related with the alloying reaction of Si and Li during the lithiation.
The charge transfer and Li+ diffusion kinetics during the lithiation process is studied systematically.
The methine proton at the chain end remained intact during the lithiation procedure.
The complete reduction of transition metal ions during the lithiation process leads to much higher capacities compared with conventional intercalation materials (e.g., graphite).
This novel architecture is expected to buffer large volume changes and effectively prevent the detachment and agglomeration of SnO2 during the lithiation and delithiation processes.
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