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Villa then put Barca ahead before Alba sealed the win in injury time.
Fernando Torres headed in two minutes after coming on as a substitute, before Alba sealed it to knock Nigeria out.
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Days before his ALBA comments, Mr Chávez accused America and Colombia of planning a "military provocation" to draw Venezuela into war and thus destroy the seeds of his desired continental socialist revolution.
Barca youth product and fellow substitute Bojan Krkic put in a low centre that Robinho seemed certain to convert before defender Alba dived across to block the shot.
When Espinoza crossed from the left, Bengtson all too easily out-leapt Alba before thumping a header beyond Manchester United's rather stunned looking goalkeeper, David de Gea.
Gomez's goal had come from an offside position and Müller should have been penalised for a foul on Jordi Alba before Robben made it 3-0.
The first goal came after he exchanged passes with his teammate Jordi Alba, before taking a perfect touch and almost casually clipping the ball into the net.
Barcelona complained that the ball had hit Zapata's arm, but it had cannoned off Jordi Alba before it hit the AC Milan player.
Suarez, who returned from a four-month ban for biting against Real a fortnight ago, squared for Neymar to tap home with 17 minutes left before the Uruguayan played Alba through for the winner on 82.
He poked in the opener from Sanchez's right-wing cross before Barca left-back Alba, after a neat one-two with Iniesta, supplied a low ball from the left for the Chilean to tuck in.
Argentina star Messi glanced in at the near post, before Alexis Sanchez tucked in Jordi Alba's low centre.
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