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Significant free energy seems to be available, as the resultant helical conformation becomes less ideal.
Specifically, the idea of the window-based interface becomes less ideal as you add more and more windows.
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This makes the existing methods become less ideal in these cases.
Since the share of Ivertical is larger now, Ishadow becomes less than Ifull (for the ideal contribution of Ivertical and Iin-plane see Supplementary Fig. 3).
As the pressure difference and temperature increased and the feed flow rate decreased, hydrogen permeation flux became less than ideal, indicating that depletion was a major factor in the hydrogen permeation behavior.
However, for more strongly non-ideal mixtures, the method becomes less reliable, giving significantly less accurate predictions of total pressure than UNIFAC.
Van der Waals one-fluid theory is successful in predicting excess properties of nearly ideal to moderately nonideal mixtures, but becomes less reliable when the mixtures become highly nonideal.
The market becomes less cheerful.
Either way, the loan becomes less profitable.
"It becomes less sensitive".
Somehow it becomes less forceful over time.
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