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After hard segment phase separation, and the resulting physical cross-linking of the PVC/TPU reactant mixture, the reaction kinetics of TPU polymerization in situ with PVC became diffusion controlled.
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Diffusivity values for growth on polysilicon were notably lower than the corresponding values on Si (100) and the growth process became diffusion-limited earlier.
When the polymerization was carried out at 60 °C, a dramatic increase in PDI (>1.4) was observed after 80% monomer conversion since RAFT addition reaction became diffusion-controlled. Increasing the polymerization temperature to 80 °C could reduce the PDI to 1.2 even at 100% monomer conversion.
Both reactions quickly become diffusion controlled.
A maximum increase in the effectiveness factor is observed in the region where the kinetics just becomes diffusion controlled.
At a platinum electrode at low potentials, < 2·6 V, the reaction is charge transfer controlled and at higher potentials the process becomes diffusion controlled.
Across the dilute PSS range, uptake mechanisms are not affected by solution concentration, although at very dilute concentration, the rate limiting process becomes diffusion in solution rather than in PEM.
The bulk CO oxidation becomes diffusion-limited by dissolved CO above ca. 0.72 V, where we observed hardly any infrared spectral features ascribed to reaction intermediates.
The Zn II) discharge becomes diffusion-controlled at more negative cathode potentials, whereas the partial nickel current densities are independent of electrode rotation speed.
The occurrence of a Turing instability means that a solution which is stable in the absence of diffusion becomes unstable when diffusion is incorporated in the system.
The two curves merge when the mixed-mode regime becomes essentially diffusion controlled in both cases.
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