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These results are significant because they demonstrate that cyclodextrin can be used to template the self-assembly of hierarchical networks of both organic and inorganic materials.
The assembly of a nucleic acid structure could be used to template the assembly of a molecular electronic elements such as molecular wires, providing a method for nanometer-scale control of the placement and overall architecture of the device analogous to a molecular breadboard.
Advances in pore size control were obtained when it was found that photonic crystals derived from bead arrays [ 5] and random bead arrangements [ 6] could be used to template diverse nanoporous, mesoporous, and microporous materials.
Since such gels are thermoreversible and would quickly dissolve at lower temperatures, it was decided to see if the cubic micellar gel phase could be used to template a crosslinked hydrogel phase to better encapsulate the micelles and to thereby provide an erodible fouling release coating.
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The interfacial properties of organic architectures, in atRA micelles, were used to template the nucleation of inorganic minerals.
Rigid cage-like molecules, like diamondoids, have been used to template the assembly of 1-D nanomaterials, and it has been hypothesized that uniquely strong van der Waals forces may explain this structure-directing behavior.
Due to the uniformity and tightly defined internal chemical environments of the pore structures, metal organic frameworks have been used to template a growing variety of reactions.
Liposomes have been used to template alginate microgel beads [ 58].
A bicontinuous phase of didodecyldimethylammonium bromide was used to template a poly methyl methacrylate) gel [ 50].
Flow chambers were prepared as described previously (Gell et al., 2010), with the exception that sea urchin axonemes (Waterman-Storer, 2001) were used to template yeast MT growth.
The resulting crystals were used to template polyacrylamide by infusing aqueous 47.9% acrylamide, 3.8% methylene bisacrylamide, and 0.4% diethoxyacetophenone (photoinitiator) solution into the interstices.
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