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Although in the case of 4 v this isomerization could be rationalized through an ester enolization pathway, this seems unlikely for other products.
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The structural basis for deleterious mutations to a structured protein is rationalized through an understanding of protein folding.
The magnetic properties of 6 have been rationalized through a ferromagnetic coupling between the central metal ion and the peripheral ones which are coupled by a smaller antiferromagnetic interaction.
While the formation of a macroscopic twin is a result of growth and coalescence of an array of small twins, the early stage growth of an incipient twin is rationalized through a slip-assisted double-cross-slip growth mechanism.
The behaviour could be rationalized through the dissociation mode concept based on a modified Henderson Hasselbalch relationship.
Various cations can be used to generate the cationized species, and highly specific cation cyclic oligomer interactions are apparent in the adducts with Na+, K+, NH4+ and H+: some of these can be rationalized through molecular modelling calculations.
The stereochemical outcome of the (S --tetramisole hydrochloride 5-catalyzed reactionS --tetramisolealized through the pretranS --tetramisolesembly shydrochloridee 3 b.
20 The variation in the computed J values can be rationalized through the extent of overlap between the densities of the Te lone pairs.
The observed microstructures were rationalized through the construction of a microstructure selection map for the Al-Ce binary system, which will be used to enable future alloy design.
This finding was rationalized through recognition of allylic A strain within the molecule and the potential electrostatic and/or hydrogen bonding interactions of the distal hydroxyl moiety.
This is rationalized through our model finding that fibers have a typically low critical aspect ratio value, which puts an upper limit to their reinforcement potential.
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