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Band at 1383 cm−1 was attributed to COO− symmetric stretching vibration group (Azouaou et al. 2010).
Following the wide hump, a reduction peak locates at ~0.55 V vs. Li+/Li, which can be attributed to the phase transition from CoO to Co and Li2O [3].
The flow stress increases obviously with cooing rate, which can be attributed to fine alpha laths and significant Hall Petch strengthening effect.
The excellent performance of ZIF-67-850 can be attributed to the synergetic effects between the Co and CoO coupled with the nitrogen doped graphitic carbon.
Such enhanced performance of the CuNFs@CoO x can be attributed to the improvement of the electrical conductivity of the CoO x by the embedded CuNF network, which creates an efficient electron percolation path between the current collector and the active material [8]. Figure 3 Galvanostatic mode at 0.15C.
The peaks at 1600 and 1420 cm−1 could be attributed to the asymmetric and symmetric stretching vibrations of the carboxylate COO– group.
Peaks around 1410 cm-1 can be attributed to O-H deformation, CH3 bending, C-O stretching of phenolic OH and COO- antisymmetric stretching.
Peaks at 1452 1408 can1 can be attributed to COO− of the carboxylate groups present in the biomass.
This phenomenon can be attributed to the higher adsorption capability of –COO− on mineral surface as well as the stronger chelation effect formed by Ca2+ and –COO−.
Peak at 1,639 couldcould be attributed to the C=O stretch of the acid groups present in thearubigins and the peak at 1,384 cm−1 could be assigned to the stretching vibration of carboxylate ion (–COO–).
These enhancements could be attributed to an increased number of reaction sites, facilitated charge transport, a decreased electrochemical double-layer capacitance, and facile stress relaxation by embedded CuNF network within the CoO x.
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